Improvements in concrete properties have been achieved by researchers with the invention of High-Performance-Concrete (HPC), which can now be improvised by using a combination of mineral admixtures. HPC is usually more brittle which can be made ductile by modifying its composition by adding fibers in the design mix, which led to the development of fiber-reinforced concrete. High-Performance-Concrete made with glass fibers and polypropylene fibers is regarded as Composite Fibre (Glass and polypropylene) Reinforced High Performance Concrete (CFRHPC). The development of cost-effective state-of-the-art procedures for producing, evaluating, and designing with CFRHPC will enhance the performance for each performance characteristic and can be reliably achieved in the field. This investigation evaluates the effect of cement being partially replaced by combined fly ash and metakaolin with glass fibers and polypropylene fibers as an addition to produce high-performance concrete with composite fiber for resistance to hydrochloric acid, magnesium sulphate, and sulphuric acid attack for 30, 60, and 90 days. The water to binder ratios (W/B) of 0.275, 0.300, 0.325, and 0.350 and an aggregate to binder ratio (A/B) of 1.75 were adopted. Fly ash and metakaolin were replaced in the range from 0% to 15% each, glass fibers were added in volume percentages from 0% to 1%, and polypropylene fibers were kept constant at 0.25%. The combined effect of fly ash and metakaolin at 5% each as replacement of cement and the addition of composite fiber dosage of glass fiber=1% and polypropylene fibers=0.25% for W/B of 0.275 was found to be the optimum combination to obtain maximum acid attack resistance, which was also justified by SEM, EDX, and XRD analysis done in this investigation. CFRHPC production minimizes enormous cement production and safeguards the environment from pollution and concrete from environmental pollution throughout its service life.