The work carried out to develop a thermodynamic model of hydrazine with the theoretically built-in capability to account for liquid-vapor phase transitions and suited for implementation in two-phase ow solvers is described. After introductory considerations of uid dynamics aspects and thermodynamic stability, the method of constructing the model based on an assumed state equation p = p(T; v) and of perfect-gas, constant-pressure, speci c-heat data available from tables of thermodynamic properties published in the literature is described. The corresponding fundamental relation is given in terms of the Helmholtz potential. Subsequently, the liquid-vapor phase equilibrium is considered and resolved via equations in line with the standard thermodynamic principles of energy minimization or entropy maximization. Aspects of model validation are discussed with respect to the liquid-vapor saturation curve, vaporization enthalpy, density, and constant-pressure speci c heat of the liquid phase. A description of other theoretical models published in the literature, together with a comparative analysis of their features relevant to the context of this work, is also included. Nomenclature A; B; C; n = state equation constants a k = interpolation coef cients, Eq. (26) a N = isothermal speed of sound c p = constant-pressurespeci c heat c v = constant-volumespeci c heat f = Helmholtz potential h = enthalpy K T = isothermal compressibility coef cient K 1 ; K 2 = integration constants M = N 2 H 4 molar mass, 32.045282£ 10 ¡3 kg ¢ mol ¡1 p = thermodynamic pressure R = hydrazine gas constant, 259.46 Jand maximum reduced pressure ½ = mass density ¿ = reduced temperature ¿ t = tangent-isothermreduced temperature 8.T / = perfect-gas constant-volume speci c heat Á = reduced speci c volume ' = reduced shifted speci c volume ' m ; ' M = left and right limits of unstable-state ranges ' np;l ; ' np;r = left and right limits of negative-pressureranges à .T / = generic function of temperature Subscripts c = critical l = saturated liquid v = saturated vapor vap = vaporization