We report on a search for the free decay component of π − stopped in water and light materials. A non-zero value of this would be an indication of anomalous νe contamination to the νe and νµ production at stopped-pion neutrino facilities. No free decay component of π − was observed in water, Beryllium, and Aluminum, for which upper limits were established at 8.2 × 10 −4 , 3.2 × 10 −3 , and 7.7 × 10 −3 , respectively.