Abstract:ABSTRACT:Experiments were carried out to study the extrusion characteristics of a vane extruder based on extensional flow.The effects of rotor speed and die pressure on output were studied and compared with a single screw extruder. The responses of melt pressure to rotor speed and die pressure were also studied in real timescale. Experimental results show that the die pressure has little effect on output, which is significantly different from that of single screw extruders. Oscillation pressure was introduced … Show more
“…A converging channel can be obtained in the circumferential direction, thus generating a dynamic elongational flow field. Materials are fed into the VPCU when the volume of the closed chamber increases and discharged when the volume decreases [22-24]. Scheme 1 Schematic presentation of vane extruder.…”
In this work, poly (lactic acid) (PLA) and elastomer ethylene-butyl acrylate-glycidyl methacrylate terpolymer (EBA-GMA) containing epoxy groups were melt-blended using a novel vane extruder. The solid-state 13 C nuclear magnetic resonance spectra ( 13 C-NMR) and the Fouriertransform infrared (FTIR) spectroscopy proved that epoxy groups of EBA-GMA reacted with the carboxylic acid or hydroxyl groups of PLA during melt blending, resulting in a grafted structure which improved the interfacial adhesion of PLA/EBA-GMA blends. The phase morphology, mechanical and thermal properties were investigated to identify the effect of EBA-GMA weight fraction on the properties of PLA/EBA-GMA blends. Thermogravimetric analysis revealed that the incorporation of EBA-GMA improved the thermal stability of PLA. The impact strength of the annealed PLA80/20EBA-GMA binary blend increased up to ten times compared without annealing process.
“…A converging channel can be obtained in the circumferential direction, thus generating a dynamic elongational flow field. Materials are fed into the VPCU when the volume of the closed chamber increases and discharged when the volume decreases [22-24]. Scheme 1 Schematic presentation of vane extruder.…”
In this work, poly (lactic acid) (PLA) and elastomer ethylene-butyl acrylate-glycidyl methacrylate terpolymer (EBA-GMA) containing epoxy groups were melt-blended using a novel vane extruder. The solid-state 13 C nuclear magnetic resonance spectra ( 13 C-NMR) and the Fouriertransform infrared (FTIR) spectroscopy proved that epoxy groups of EBA-GMA reacted with the carboxylic acid or hydroxyl groups of PLA during melt blending, resulting in a grafted structure which improved the interfacial adhesion of PLA/EBA-GMA blends. The phase morphology, mechanical and thermal properties were investigated to identify the effect of EBA-GMA weight fraction on the properties of PLA/EBA-GMA blends. Thermogravimetric analysis revealed that the incorporation of EBA-GMA improved the thermal stability of PLA. The impact strength of the annealed PLA80/20EBA-GMA binary blend increased up to ten times compared without annealing process.
In this work, a novel melt mixing method and its corresponding mixing device are developed. The extensional/shear strength ratio of the device can be controlled by adjusting its eccentricity. The structure and working principle of the device are introduced in detail. Carbon fiber (CF)/polyamide 6 (PA6) composites are prepared via this novel mixing device. The influences of eccentricity and mixing time on the morphology, CF length, thermal, mechanical, and electrical properties of CF/PA6 composites are studied. Scanning electron microscopy results show that CFs uniformly disperse in the matrix and interfacial adhesion between CFs and PA6 is improved. It is observed that CF length and its distributions can be optimized by changing eccentricity. The maximum average fiber length is about 351 μm. Differential scanning calorimetry results exhibit that the Xc increases 6.5% when eccentricity is 2 mm. Mechanical test results show tensile strength and modulus increase first and then decrease with the increasing eccentricities or mixing time. Electrical property measurement shows an obvious increase when eccentricity is 2 mm due to good fiber dispersion and long fiber retention length. The experimental results indicate that the novel mixing method and its corresponding apparatus provide an environment‐friendly and effective way to prepare polymer‐based composites.
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