2024
DOI: 10.1007/s10008-024-06086-z
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Experimental study on Na+ conductivity in NaAlBr4 and atomic-scale investigation of Na+ conduction

Reona Miyazaki,
Masanobu Nakayama,
Takehiko Hihara

Abstract: The ionic conduction properties of Li/Na metal halides have been extensively studied, with recent attention turning towards Al-based systems. However, limited studies have focused on alkali Al bromides. In this study, we explored the Na+ conduction properties of NaAlBr4. Conductivity measurements at 30 °C revealed a Na+ conductivity of 1.2 × 10−5 S/cm, surpassing that of isostructural NaAlCl4 threefold. Molecular dynamics (MD) simulations to elucidate the conduction mechanisms revealed that Na+ conduction was … Show more

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