Currently, research on enhancing imbibition oil recovery
in tight
oil reservoirs through the ion-tuning technique remains limited. Two
critical parameters for capillary imbibition are the wettability and
interfacial tension between oil and water. In this investigation,
we manipulate the properties of two types of formation water for both
aged and unaged samples by diluting brine and altering ion composition.
Subsequently, we employ captive and pendant-drop methods to assess
rock wettability and interfacial tension under varied brine conditions.
Additionally, we elucidate the primary mechanisms underlying changes
in rock wettability and interfacial tension. Meanwhile, we analyze
capillarity characteristics and assess the relative significance of
wettability and interfacial tension. Results indicate that there is
a critical interfacial tension with progressive dilution of two types
of formation water. However, modifying ion composition leads to a
complex trend in interfacial tension, which can be explained qualitatively
through the Gibbs adsorption isotherm. For unaged samples, the contact
angle demonstrates a pronounced water-wet characteristic, showing
a nonmonotonic trend with respect to dilution times. Remarkably, the
rock surface exhibits the strongest water-wet, particularly evident
in the case of FW-10, largely influenced by variations in interfacial
tension. Conversely, aged samples demonstrate strong oil-wet, with
a critical salinity resulting in the lowest contact angle, while altering
brine ion types can alter rock wettability from strongly oil-wet to
intermediate-wet, which is not sufficient to result in the wettability
alteration. The removal of multivalent cations is proposed as the
most effective method for wettability modification. Furthermore, capillarity
variations among different brine cases are primarily contingent upon
contact angle changes, and interfacial tension does not have a significant
change when regulating the brine properties. Consequently, we emphasize
the significance of wettability in the adoption of ion-tuned brine
techniques for tight oil reservoirs. Overall, our study underscores
the potential of reasonably regulating brine properties to enhance
capillarity and, thereby, improve imbibition oil recovery.