Space cooling energy consumption in residential buildings has tripled globally over the past three decades, leading to a significant increase in greenhouse gas (GHG) emissions and building operating costs. To reduce building cooling energy consumption, cooling energy can be recovered from domestic cold water (DCW) for space cooling by circulating DCW through thermally massive walls (herein “DCW-wall”) before regular household consumption (e.g., showers). This approach is more effective in cold climate regions since the DCW is cooler in these regions, yet its engineering design and effectiveness have not been evaluated previously. This study evaluated the cooling potential of DCW-walls in different operation scenarios (e.g., inlet temperatures, zone temperatures, and piping configurations). A typical DCW usage pattern and a daily amount of 1200 L were selected for evaluation. Three-dimensional transient thermal simulations were used to obtain the water outlet temperatures, average wall surface temperatures, and cooling potentials. The results showed that a DCW wall with a spiral piping configuration and DCW inlet at 12 °C can deliver 21.92 MJ of cooling energy daily to a zone at 25 °C. This amount of free energy can cover up to approximately 11% of the annual cooling energy demand of a four-person dwelling in Toronto, Canada, which has a warm and humid summer.