Large-scale modern wind turbines at standstill are prone to vortex-induced vibration (VIV). In this study, coupled fluid–solid dynamics of the wind turbine airfoil at a 90° attack angle are performed using the detached eddy simulation. The fully developed vibration responses with different structural dampings are explored in detail. The frequency lock-in regime is determined, and the corresponding phase differences between the lift and displacement are presented with the Lissajous curve. The dominant surface pressure mode and wake flow exhibit significant three-dimensional flow characteristics in unlock-in conditions, while a strong spanwise correlation in lock-in conditions is detected. The pressure fluctuation on the suction side in the lock-in state is observed to be more significant than in the unlock-in state. The effect of the distributed airfoil surface pressure on VIV is evaluated by considering the contribution value and the cyclic aerodynamic work density. With the decrease in structural damping, the aerodynamic work near the leading edge gets enhanced and the negative work region is reduced, leading to a higher amplitude of VIV. The beat vibration and hysteresis behavior at the critical reduced velocity are also analyzed in both the time domain and frequency domain.