Exploiting Hydrogen Bonding to Direct Supramolecular Polymerization at the Air/Water Interface

Argudo, Pablo G.; Coelho, João Paulo; López-Sicilia, Irene; Guerrero‐Martínez, Andrés; Martín‐Romero, María T.; Camacho, Luis; Fernández, Gustavo; Giner‐Casares, Juan J.

doi:10.1002/cnma.202200448

ChemNanoMat

2022

DOI: 10.1002/cnma.202200448

|View full text |Cite

Exploiting Hydrogen Bonding to Direct Supramolecular Polymerization at the Air/Water Interface

Pablo G. Argudo

João Paulo Coelho

Irene López-Sicilia

et al.

Abstract: Supporting information for this article is given via a link at the end of the document.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 42 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Quantifying Hydrogen-Bonding Interactions in the Self-Assembly of Photoresponsive Azobenzene Amphiphiles at the Air–Water Interface

Samal,

Maiti,

Patel

et al. 2024

J. Phys. Chem. Lett.

View full text Add to dashboard Cite

Amphiphilic azobenzene molecules offer ample scope to design functional supramolecular systems in an aqueous medium that can be controlled by light. Despite their widespread applications in photopharmacology and optoelectronics, the self-assembly pathways and energy landscapes of these systems are not well understood. Here, we report combined molecular dynamics (MD) simulation and surface manometry studies on a specially designed alkylated, meta-substituted azobenzene derivative to quantify the hydrogen-bonding interactions in the self-assembled monolayers of its photoisomers. The z-density profile, radial distribution function, order parameters, and hydrogen bond analyzed using MD simulations corroborated the experimental observations of changes in surface pressure, dipole moment, and thickness of the monolayers. Even a small change in the number of hydrogen bonds in the molecule–molecule and molecule–water interactions causes significant changes in the monolayer properties. These results are fundamentally important for engineering photoresponsive molecules with tailored properties for applications in targeted drug delivery and other industrial applications.

show abstract

Quantifying Hydrogen-Bonding Interactions in the Self-Assembly of Photoresponsive Azobenzene Amphiphiles at the Air–Water Interface

Samal,

Maiti,

Patel

et al. 2024

J. Phys. Chem. Lett.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Exploiting Hydrogen Bonding to Direct Supramolecular Polymerization at the Air/Water Interface

Abstract: Supporting information for this article is given via a link at the end of the document.

Cited by 1 publication

References 42 publications

Quantifying Hydrogen-Bonding Interactions in the Self-Assembly of Photoresponsive Azobenzene Amphiphiles at the Air–Water Interface

Quantifying Hydrogen-Bonding Interactions in the Self-Assembly of Photoresponsive Azobenzene Amphiphiles at the Air–Water Interface

Contact Info

Product

Resources

About