Coal spontaneous combustion (CSC) is a multifaceted research domain that has been widely explored in the literature, ranging from analytical and numerical modeling to the development of fire suppression materials and methods. A comprehensive review of the literature has revealed several distinct research trajectories, or “roadmaps”, identified through criteria such as the volume of studies addressing each theme, the presence of review papers dedicated to a specific roadmap, and the explicit mention of coal spontaneous combustion in the title or keywords. This classification framework has outlined six primary roadmaps: (1) spread, quantification, and impact; (2) mechanisms, models, factors, and parameters; (3) experimental studies and models; (4) detection, monitoring, and prediction; (5) prevention and control; and (6) applications. While interconnections exist between these roadmaps, and all ultimately converge towards roadmap 5 (prevention and control), each roadmap constitutes a distinct research cluster. The focus of this review is on roadmap 4, specifically addressing the methods and technologies for detection, monitoring, and prediction of CSC events. This review encompasses studies published from 2010 to the present, providing a thorough examination of the various detection techniques employed, with particular emphasis on their limitations and the strategies proposed to overcome these challenges. A critical analysis highlights the key advantages and disadvantages of each category of techniques, offering insights into their practical applications and the potential for future advancements in this field. The present review aims to contribute to the refinement of detection and monitoring methods for CSC, with the goal of enhancing early detection capabilities and improving fire management strategies.