Compositional zoning and dissolution in cement is a direct
response to the fluctuation of pore water chemistry, the variation of
which during burial can be controlled by many factors, including the
interaction between pore water and rock-forming minerals and the
mixing of fluids from different origins. This paper suggests that
tectonic activity can, by altering the hydraulic gradient, also
influence pore water chemistry and lead to dissolution of cement,
made clear by zoning within siderite crystals. Three different stages
of siderite cement have been described from the Tirrawarra Sandstone
in the Moorari and Fly Lake fields of the southern Cooper Basin, here
referred to as S1 (early), S2 (middle), and S3 (late). Ragged
dissolution surfaces separate the main phases, occurring after
precipitation of S1 and S2 with incipient dissolution suggested
within S2. Back-scattered electron (BSE) images and electron
microprobe analyses clearly differentiate each main phase of
siderite. S1 is a homogeneous, iron-rich siderite whereas S2 displays
patchy compositional zoning associated with several minor dissolution
stages, and S3 commences with even compositional banding and grades
into a thick homogeneous phase in the terms of composition.Isotope analyses and fluid inclusion studies indicate that S1
formed at a temperature around 30 °C, S2 precipitated at a
minimum temperature of 68 °C, and S3 formed around 102 °C.
The heterogeneous, pitted and zoned S2 is thought to have formed
during a time of active tectonism in the Cooper Basin, whereas the
evenly banded nature of S3 suggests that it precipitated during a
quiet tectonic period when pore waters largely remained relatively
constant. It appears that siderite cements in the Tirrawarra
Sandstone record tectonic activity in the form of irregular growth
and dissolution highlighted by compositional zoning with stages of
strong dissolution recording particularly active times when pore
waters changed composition dramatically. Some zoning could be related
in part to tectonic pulses. The temperature recorded by each of the
siderite stages allows their precipitation to be tied to a burial
history curve, and by making some simple assumptions about that
history, the timing of cementation can be estimated. This can be an
additional tool for calibrating the thermal history of an
area.