Exploration of two types of maximum–minimum flash point behavior of ternary mixtures

Liaw, Horng‐Jang; Hsu, Wei-Chih; Lakzian, Kazem

doi:10.1016/j.jlp.2022.104915

Journal of Loss Prevention in the Process Industries

2022

DOI: 10.1016/j.jlp.2022.104915

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Exploration of two types of maximum–minimum flash point behavior of ternary mixtures

Horng‐Jang Liaw¹,

Wei-Chih Hsu²,

Kazem Lakzian³

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Cited by 3 publications

(1 citation statement)

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“…Most recently, Liaw and collaborators 68 exploited the FP behavior of phenol + cyclohexanol + isoamyl butyrate and phenol + acetophenone + 1-octanol ternary systems. The authors mentioned that these systems also presented both MaxFPB and MinFPB: the binary systems formed of phenol + cyclohexanol (MaxFPB), phenol + acetophenone, and phenol + 1-octanol exhibited MaxFPB, while cyclohexanol + isoamyl butyrate and acetophenone + 1-octanol showed MinFPB.…”

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confidence: 99%

Mixture Flash Point Calculation: Recent Advances and a Closer Look at Biodiesel

Costa do Nascimento,

Souza,

Hentges

et al. 2024

ACS Chem. Health Saf.

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To safely handle, transport, and store flammable or combustible liquids, such as biodiesel and its blends, it is important to have knowledge of a few physical-chemical properties. The Flash Point is an important one, as it is related to the flammability of the fuel blend. It can be experimentally measured through open cup or closed cup standard procedures. However, due to the usual scarcity of experimental data for multicomponent systems, developing a model to predict flash points of mixtures is of interest. To do so, there are a few possible approaches, which include empirical regression of data, vapor pressure-based methods, and QSPR. When it comes to mixtures, the most popular modeling method is based on vapor pressure, which usually employs LeChatelier's rule and vapor−liquid equilibria (VLE) calculations to flash point prediction. Generally, a γ−φ approach is adopted to describe the VLE behavior, although some authors have shown interest in φ−φ approaches. In recent years, studies on QSPR for FP prediction of mixtures have evolved, which represents an advance toward more generalized FP prediction models. Additionally, COSMO type models have been gaining attention in FP prediction, usually associated with vapor pressure models or even empirical models. When it comes to biodiesel though, not much progress has been made since 2014, with just a few works being published since then. This paper seeks to review advances made in FP prediction methods for mixtures in general, while giving attention to those involving biodiesel and petro-diesel.

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confidence: 99%

Mixture Flash Point Calculation: Recent Advances and a Closer Look at Biodiesel

Costa do Nascimento,

Souza,

Hentges

et al. 2024

ACS Chem. Health Saf.

View full text Add to dashboard Cite

show abstract

Small scale pool fires: The case of toluene

De Liso,

Pio,

Salzano

2024

Journal of Loss Prevention in the Process Industries

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Flash point prediction of binary partially and totally miscible alcohol-water mixtures by various equation of states and experimental validation

Yousefi

Mansouri

Salmani

et al. 2023

Chemical Engineering Communications

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Exploration of two types of maximum–minimum flash point behavior of ternary mixtures

Cited by 3 publications

References 32 publications

Mixture Flash Point Calculation: Recent Advances and a Closer Look at Biodiesel

Mixture Flash Point Calculation: Recent Advances and a Closer Look at Biodiesel

Small scale pool fires: The case of toluene

Flash point prediction of binary partially and totally miscible alcohol-water mixtures by various equation of states and experimental validation

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