Cuprous
oxide (Cu2O) is a promising photocathode material
for photoelectrochemical (PEC) water splitting. Recently, the PEC
performances of Cu2O-based devices have been considerably
improved by introducing nanostructures, semiconductor overlayers,
and hydrogen evolution reaction (HER) catalysts. However, Cu2O devices still suffer from poor stability in aqueous solution, especially
in strong acidic or alkaline conditions, despite the use of an intrinsically
stable oxide overlayer as a protection layer. Thus, it is essential
to fully understand the stability of the entire Cu2O photocathodes
in these conditions for establishing suitable protection strategies
to achieve durable PEC water splitting. In this work, the stability
of bare and protected Cu2O nanowire (NW) photocathodes
was evaluated in detail using microscopy techniques and compositional
analyses. The insights gained in this work will guide the design and
synthesis of durable photoelectrodes for PEC water splitting.