Exploring Coordination of Neodymium in Ionic Liquid: Insights to Guide Sustainable Recovery

Abstract

Neodymium is a critical metal essential for advancing sustainable clean energy technologies, as it is a crucial component in the manufacturing of NdFeB permanent magnets, part of wind turbines, electric vehicles, and advanced electronics. Its recovery from secondary sources using electrochemical deposition in ionic liquids has the potential to sustainably achieve a closed-loop alternative to obtain the metal. The presence of water in low, specific concentrations in ionic liquid has been previously shown to catalyze electrodeposition of Nd with amplified current densities and easier reduction of Nd3+, but the structure(s) of the metal/mixed-ligand species that led to this amplification was previously only hypothesized. Stringently benchmarked quantum chemical calculations reveal a complex potential energy landscape that underpins the structural transformations arising from the introduction of water into the coordination sphere of Nd3+ surrounded by bis(trifluoromethanesulfonyl)imide (TFSI) anions. Three distinct changes were observed in the Nd3+-TFSI– complexes upon addition of water: (i) cis/trans transformation of TFSI, (ii) transition from bidentate to monodentate TFSI– coordination, and (iii) displacement of TFSI– ligands by water. Energetic analyses of these structural changes can explain experimentally observed water-loading effects regarding the ease of electrochemical reduction of Nd3+ and its deposition. These outcomes provide a platform for tuning ionic liquid media compositions to enhance rare-earth metal recovery.

Ionometallurgy: an academic exercise or promising approach?

“…A water content of 0.4 wt% enhanced neodymium reduction by the reorganization of the coordination environment of the metal ion by means of a varied cis / trans coordination ratio, with [NTf 2 ] − rather acting as a monodentate ligand and partial [NTf 2 ] − replacement. 86,87…”

Recent Uses of Ionic Liquids in the Recovery and Utilization of Rare Earth Elements

“…It was shown that the electrodeposition of Nd(III) in ionic liquids media is dependent of the presence of water in the system. In fact, the presence of water catalyzed the electrodeposition of the rare earth, thus, the introduction of water into the coordination sphere of the complex formed by this REE and bis(trifluoromethanesulfonyl)imide [NTf2 -] anions and its influence on the metal deposition was investigated [27]. The addition of water produced various effects in the Nd 3+ [NTf2 -] complexes affecting the Nd 3+ electrochemical reduction, these effects can be summarized as: cis/trans transformation of the anion, change from bidentate to monodentate forms in the coordination mode of the anion and preferably coordination of water with the transition metal.…”