Exploring enantioselective recognition of dTMP-Co-bpe coordination polymer for natural amino acids using molecular simulations and circular dichroism

Abstract

The 1D homochiral coordination polymer (complex 1){[Co(dTMP)(bpe)2(H2O)3]•9H2O}n was constructed by using 2′-deoxy thymidine 5′-monophosphate disodium salt (dTMP.2Na), and auxiliary ligand BPE (1,2-Bis(4-pyridyl)ethene) and characterized by single-crystal XRD, PXRD, IR, UV-visible,...