2024
DOI: 10.1021/acs.iecr.4c01533
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Exploring the Kinetics of Solution Polymerization of Butyl Acrylate for Tailoring a Microstructure at Elevated Temperatures

Atefeh Hamidi,
Alireza Mahjub,
Hesam Makki

Abstract: The production of low molar mass polyacrylates commonly involves a starved-feed semibatch free radical polymerization process carried out at elevated temperatures. The kinetics of free radical polymerization of acrylates at higher temperatures introduces complexity, attributed to secondary reactions like backbiting and Beta-Scission, which affect the molecular structure and molar mass. In this study, the Monte Carlo method is utilized to simulate the free-radical solution polymerization of butyl acrylate at hi… Show more

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