2024
DOI: 10.1021/acs.inorgchem.3c03744
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Exploring the Performance Improvement for CO2 Chemical Fixation in Zn/ZnMg-MOFs

Lin Ding,
Ning Xu,
Yakun Wu
et al.

Abstract: A new 3D zinc-based metal–organic framework {[Zn7L2(DMF)3(H2O)­(OH)2]·5DMF} n (1) (H6L = 5,5′,5″-(methylsilanetriyl) triisophthalic acid) was constructed with an organosilicon-based linker, where H6L is a tetrahedral structure furnished with rich −COO– chelating sites for Zn­(II) immobilization. Compound 1 exhibited two types of irregular one-dimensional channels and a three-dimensional skeleton with large specific surface area, making it a promising catalytic platform. Moreover, by incorporation of the secon… Show more

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Cited by 3 publications
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“…Heterogeneous catalysts are hence more attractive candidates in this area for their facile separation, simplicity in operation, and good recycling performance. The explored heterogeneous catalysts include the heterogenization of metal complexes on various supports, metal–organic frameworks, precious-metal-based catalysts, and metal oxides. Despite the great progress already achieved, there is still much room for further development of an advanced and cost-effective catalyst for the cycloaddition of CO 2 with epoxides.…”
Section: Introductionmentioning
confidence: 99%
“…Heterogeneous catalysts are hence more attractive candidates in this area for their facile separation, simplicity in operation, and good recycling performance. The explored heterogeneous catalysts include the heterogenization of metal complexes on various supports, metal–organic frameworks, precious-metal-based catalysts, and metal oxides. Despite the great progress already achieved, there is still much room for further development of an advanced and cost-effective catalyst for the cycloaddition of CO 2 with epoxides.…”
Section: Introductionmentioning
confidence: 99%