Exploring the potential of triple conducting perovskite cathodes for high-performance solid oxide fuel cells: a comprehensive review
Lingxiao Lu,
Yu Liu,
Hualiang Zhang
et al.
Abstract:Solid oxide fuel cells (SOFCs) represent a class of energy conversion devices that exhibit exceptional efficiency in the direct conversion of chemical energy from diverse fuel sources into electricity. The...
“…However, it's worth noting that these cobalt-based cathodes are plagued by issues such as cobalt evaporation and high thermal expansion coefficients, which pose challenges to the long-term stable operation of H-SOFCs. 8–10 Subsequently, cobalt-free cathodes for H-SOFCs have emerged, offering both excellent chemical stability and appropriate ORR activity, presenting a promising solution to address the challenges posed by cobalt-based cathodes. 11–14…”
The Zn-doped BCF36 cathode boosts proton conductivity, lowers hydration energy and achieves a peak power density of 998.6 mW cm−2 at 600 °C with a polarization resistance of 0.151 Ω cm2 for a single cell with the BCFZ10 cathode.
“…However, it's worth noting that these cobalt-based cathodes are plagued by issues such as cobalt evaporation and high thermal expansion coefficients, which pose challenges to the long-term stable operation of H-SOFCs. 8–10 Subsequently, cobalt-free cathodes for H-SOFCs have emerged, offering both excellent chemical stability and appropriate ORR activity, presenting a promising solution to address the challenges posed by cobalt-based cathodes. 11–14…”
The Zn-doped BCF36 cathode boosts proton conductivity, lowers hydration energy and achieves a peak power density of 998.6 mW cm−2 at 600 °C with a polarization resistance of 0.151 Ω cm2 for a single cell with the BCFZ10 cathode.
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