Arica is a coastal city located in northern Chile, in the Atacama Desert. The behavior of surface temperatures in the city between 1985 and 2019 was studied using Landsat satellite images, leading to the identification of surface urban heat islands (SUHI), surface urban cold islands (SUCI), and average temperature zones. The higher intensities of the SUHI reach values of almost 45 °C and the SUCI lower values are below 13 °C. From the socioeconomic characterisation of the population based on indicators retrieved from the 2012 and 2017 population censuses, we identified that during the study period there was a lower presence of SUHI, but these were linked to spaces of lower socioeconomic level and, for the most part, would form new urban spaces within the city. On the other hand, SUCI had a greater spatial presence in the study area and in the urban morphology, being found mostly in areas of high socioeconomic level and in consolidated spaces with few possibilities of generating new constructions.