Exploring the viability of noble gas endohedral siladodecahedranes and its perhalogenated derivatives

Exploring the Nature of Chemical Bonding between Noble Gases and Hypercoordinate Group 13 Compounds: Beyond Boron

“…The chemical bond of those molecules has been systematically studied, even with the possibility of the formation of C–He and C–Ne bonds at very low temperatures. Additionally, it is known that heavier gases form hypercoordinated compounds with fluorine. , On the other hand, the chemical bonding of noble gases with other atoms is not only limited to elements of period 2 of the periodic table but also the bonding capacity with silicon, sulfur, chlorine, among others − has been explored. However, the ability of noble gases to bond hypercoordinated containing heavier group 13 elements has not been systematically studied.…”