Studying the critical phenomena accompanying the order‐disorder phase transition (β‐δ, β‐γ) in NH4Cl1–xBrx mixed crystals especially at multicritical points, the velocity and the attenuation of the longitudinal sound wave at 10 MHz propagating along the [100] direction are measured as a function of mole fraction (x = 0 to 1) and of temperature (310 to 200 K). A large critical softening of velocity is observed in the disordered β‐phase of both β‐δ and β‐γ transitions. The results indicate that the fluctuations of two order parameters corresponding to the δ‐ and γ‐phases have a mutual interaction through elastic strain. The critical softening is expressed by a simple power low: [V(∞)‐V(0)]/V(∞) = A[(T – T0)/T] q. The critical index, q, varies with x. The fluctuations of the two order parameters in the disordered β‐phase are enhanced near the triple point, and are suppressed near the tricritical point.