The
control of soot emission from diesel vehicles is of extraordinary
importance to the environment, and catalytic removal of soot is a
highly effective and clean method. Here, we report a novel, non-noble
metal catalyst for application in the catalytic combustion of soot
with superb activity and resistance to H2O and SO2. MnO
x
oxide was prepared via a hydrothermal method, and then, Cs and Co were loaded on MnO
x
by impregnation. The 5%Cs/1%Co/MnO
x
catalyst displayed excellent catalytic activity
with values of T
10 (332 °C), T
50 (371 °C), and T
90 (415 °C) under loose contact. The as-prepared catalysts
were investigated by X-ray powder diffraction (XRD), transmission
electron microscopy (TEM), H2 temperature-programmed reduction
(TPR), O2 temperature-programmed desorption (TPD), X-ray
photoelectron spectroscopy (XPS), and X-ray absorption fine structure
(XAFS). The results suggest that, after the introduction of Cs and
Co into the MnO
x
oxide, more NO2 molecules take part in soot oxidation, exhibiting higher NO2 utilization efficiency; this is due to the synergistic effects
of multiple components (Cs, Co, and Mn) promoting the generation of
more surface-active oxygen and then accelerating the reaction between
NO2 and soot. This study provides significant insights
into the development of high-efficiency catalysts for soot oxidation,
and the developed 5%Cs/1%Co/MnO
x
catalyst
is a promising candidate for application in diesel particulate filters.