Extension to the Construction of
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 OR
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 OCF
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 H
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 ,
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 OCFH
 2
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 OCH
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 CF
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Lin, Jin‐Hong; Xiao, Ji‐Chang

doi:10.1002/9783527824342.ch10

Emerging Fluorinated Motifs 2020

DOI: 10.1002/9783527824342.ch10

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Extension to the Construction of OR _f Motifs ( OCF ₂ H , OCFH ₂ , OCH ₂ CF ₃ ,

Jin‐Hong Lin

Ji‐Chang Xiao

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Cited by 4 publications

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Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

Kordnezhadian

Zogu

et al. 2022

Chemistry A European J

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Pentafluorosulfanyl (SF 5 )-containing compounds and corresponding analogs are a highly valuable class of fluorine-containing building blocks owing to their unique properties. The reason for that is the set of peculiar and tremendously beneficial characteristics they can impart on molecules once introduced onto them. Despite this, their application in distinct scientific fields remains modest, given the extremely harsh reaction conditions needed to access such compounds. The recent synthetic approaches via SÀ F, and CÀ SF 5 bond formation as well as the use of SF 5containing building blocks embody a "stairway-to-heaven" loophole in the synthesis of otherwise-inaccessible chemical scaffolds only a few years ago. Herein, we report and evaluate the properties of the SF 5 group and analogs, by summarizing synthetic methodologies available to access them as well as following applications in material science and medicinal chemistry since 2015.

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Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

Kordnezhadian

Zogu

et al. 2022

Chemistry A European J

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N-Difluoromethylation of N-pyridyl-substituted anilines with ethyl bromodifluoroacetate

et al. 2022

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Accessing structurally diverse aryl difluoromethyl ethers with bromo(difluoro)acetic acid

Kumawat,

Natte

2024

Chem. Commun.

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Extension to the Construction of OR _f Motifs ( OCF ₂ H , OCFH ₂ , OCH ₂ CF ₃ ,

Cited by 4 publications

References 99 publications

Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

N-Difluoromethylation of N-pyridyl-substituted anilines with ethyl bromodifluoroacetate

Accessing structurally diverse aryl difluoromethyl ethers with bromo(difluoro)acetic acid

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Extension to the Construction of OR f Motifs ( OCF 2 H , OCFH 2 , OCH 2 CF 3 ,

Cited by 4 publications

References 99 publications

Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

N-Difluoromethylation of N-pyridyl-substituted anilines with ethyl bromodifluoroacetate

Accessing structurally diverse aryl difluoromethyl ethers with bromo(difluoro)acetic acid

Contact Info

Product

Resources

About

Extension to the Construction of OR _f Motifs ( OCF ₂ H , OCFH ₂ , OCH ₂ CF ₃ ,