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The effects of Mg microadditions on the high-temperature/low stress (1255 K/200 MPa) creep properties and fracture behavior of a Mar-M247 superalloy were investigated in this study. The results of quantitative statistical analyses showed that when Mg microadditions up to 50 ppm were made, the MC carbides located at grain boundaries (designated GB MC) were significantly refined and spheroidized and the number of MC carbides decreased. In addition, the M 23 C 6 carbides present on GBs dramatically increased with increasing Mg contents up to 50 ppm, and the creep resistance was enhanced under the test condition of 1255 K/200 MPa. However, the creep performance of a Mar-M247 superalloy containing 80 ppm Mg deteriorated due to the formation of an extremely large amount of MC carbide and a decrease in the number of M 23 C 6 carbides at GBs. The cracks mainly initiated and propagated along GBs in both the Mg-free and Mg-containing Mar-M247 superalloys under 1255 K/200 MPa, and the finial rupture was caused by intergranular fracture. Under the present creep condition, the optimal Mg microaddition to a Mar-M247 superalloy should be 30 to 50 ppm.
The effects of Mg microadditions on the high-temperature/low stress (1255 K/200 MPa) creep properties and fracture behavior of a Mar-M247 superalloy were investigated in this study. The results of quantitative statistical analyses showed that when Mg microadditions up to 50 ppm were made, the MC carbides located at grain boundaries (designated GB MC) were significantly refined and spheroidized and the number of MC carbides decreased. In addition, the M 23 C 6 carbides present on GBs dramatically increased with increasing Mg contents up to 50 ppm, and the creep resistance was enhanced under the test condition of 1255 K/200 MPa. However, the creep performance of a Mar-M247 superalloy containing 80 ppm Mg deteriorated due to the formation of an extremely large amount of MC carbide and a decrease in the number of M 23 C 6 carbides at GBs. The cracks mainly initiated and propagated along GBs in both the Mg-free and Mg-containing Mar-M247 superalloys under 1255 K/200 MPa, and the finial rupture was caused by intergranular fracture. Under the present creep condition, the optimal Mg microaddition to a Mar-M247 superalloy should be 30 to 50 ppm.
The effects of microadditions of Mg on the mechanical behavior and fracture mechanism of MAR-M247 superalloy were investigated in this study. The microstructural observations and image analysis showed that a Mg microaddition ranging from 30 to 80 ppm significantly changed the primary MC carbide characteristics and inhibited the scriptlike carbide formation. After a 80 ppm Mg addition, the elongation measured at 1172 K increased over 3 times found that for the Mg-free MAR-M247 superalloy. The creep life and rupture elongation of the MAR-M247 superalloy with 80 ppm Mg was also improved up to 3 to 5 times that of the alloy without Mg during a 1033 K/724 MPa creep test. The fracture analyses demonstrated that cracks were mainly initiated and propagated at the interface of scriptlike MC carbides in the Mg-free MAR-M247 superalloy at elevated temperatures. The Mg microaddition effectively refined and spheroidized these coarse carbides so that a change in the crack initiation occurred from the carbide/matrix interface to that along the ␥-␥' eutectic. Interfacial analysis using Auger electron spectroscopy illustrated that Mg segregated to the interface of the MC carbide/matrix, causing a change in the morphology and interfacial behavior of the carbides. This improvement contributed to a prolonged rupture life and upgraded the moderate temperature ductility of the MAR-M247 superalloy.
been recognised for about 70 years. Merica and Waltenberg2 attributed the effect of S to the formation The present state of knowledge on the effects of C, of a low melting point eutectic with Ni. Similarly, B, S, and P on the weldability of Ni base superalloys is reviewed. Consideration is also White et al.3 quoting some Russian work have shown given to the effects of Mg and the rare earths on reduced values of reduction in area with increasing S weldability, though the data are sparse and the concentrations (10-140 at. ppm) in Ni in the tempermanufacturing route often not defined. From the ature range 600-1000°C (Fig. 1). A considerable analysis, B is considered to be the most influence of S on ductility is seen when Á20 ppm of detrimental element to the weldability, with lesser S is added to the Ni. effects from C and S. The data on P are limited, but The effects of minor elements on the weldability of recent results show that P has a variable effect on superalloys have been investigated since the 1950s, weldability, being most detrimental in low C alloys with the research of Pease,4 for example, showing (0•01 wt-%), and less of a problem in C levels that P, S, and B were detrimental. Carbon was >0•03 wt-% and above. Consideration is also given to the effects of heat treatment in influencing considered to have a variable effect along with Al, Ti, solute segregation to the grain boundary and on Mo, and Si. Magnesium was considered beneficial, grain growth. The potential effects of two or more though Zr was considered detrimental. Pease's results elements on grain boundary microchemistry and formed the basis for minor element control in the its effects on weldability are also discussed. early days of superalloy metallurgy, especially for IMR/347 wrought air melted alloys of Ni.In the literature, results of the research on the effect
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