The impossibility of deterministic and error-free discrimination among nonorthogonal quantum states lies at the core of quantum theory and constitutes a primitive for secure quantum communication. Demanding determinism leads to errors, while demanding certainty leads to some inconclusiveness. One of the most fundamental strategies developed for this task is the optimal unambiguous measurement. It encompasses conclusive results, which allow for error-free state retrodictions with the maximum success probability, and inconclusive results, which are discarded for not allowing perfect identifications. Interestingly, in high-dimensional Hilbert spaces the inconclusive results may contain valuable information about the input states. Here, we theoretically describe and experimentally demonstrate the discrimination of nonorthogonal states from both conclusive and inconclusive results in the optimal unambiguous strategy, by concatenating a minimum-error measurement at its inconclusive space. Our implementation comprises 4-and 9-dimensional spatially encoded photonic states. By accessing the inconclusive space to retrieve the information that is wasted in the conventional protocol, we achieve significant increases of up to a factor of 2.07 and 3.73, respectively, in the overall probabilities of correct retrodictions. The concept of concatenated optimal measurements demonstrated here can be extended to other strategies and will enable one to explore the full potential of high-dimensional nonorthogonal states for quantum communication with larger alphabets.