Extraction and Separation of Zirconium Using 1-Octanol

Kabangu, M. J.; Crouse, Philip

doi:10.1007/s42461-019-0089-z

Cited by 3 publications

(5 citation statements)

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the current study, the use of TBP-Dodecane extractants does not form a third phase which can inhibit the separation process in determining the organic phase and water phase for the separation of Zr and Hf. From the results of the study, a significant %Zr extraction value was obtained which was 97.32 % when compared to the research conducted by Kabangu et al 16) when compared with research conducted by Kabangu et al 16) using 2-octanol extractants with hydrochloric acid media with a value of 96.58 % at an O/A ratio of 1:1. The use of organic phase composition is much greater when compared to the 1:5 O/A ratio for TBP-Dodecane extractants.…”

Section: Effect Of Ratio Organic and Aqueous Phase (O/a)mentioning

confidence: 54%

“…Extraction is carried out by shaking at a variation in the O/A ratio of 1:1; 1:2; 1:3; 1:4; 1:5; 2:1; 3:1; 4:1; 5:1 with variations in shaking time (15,30,45,60, and 75 min). 2 separate phases were obtained, namely the organic phase and the water phase.…”

Section: Extraction Of Zr and Hfmentioning

confidence: 99%

“…Extraction was carried out at a stirring setting of 200 rpm for 75 min with a concentration of nitric acid used 1 M. TBP-Dodecane mixture as an organic phase was mixed with zirconium nitrate feed solution. In research conducted by Kabangu et al 15) stated that the use of TBP extractants can be combined with MIBK to prevent the formation of the third phase. In the current study, the use of TBP-Dodecane extractants does not form a third phase which can inhibit the separation process in determining the organic phase and water phase for the separation of Zr and Hf.…”

Section: Effect Of Ratio Organic and Aqueous Phase (O/a)mentioning

confidence: 99%

“…14) Several researchers have conducted effective research on the separation of Zr and Hf. Kabangu et al 15) succeeded in separating Zr and Hf using 2-octanol extractants (C 8 H 18 O). Zirconium and hafnium have a separation factor of 9.2 under these circumstances, and the highest extraction percentage is 96.58 %.…”

Section: Introductionmentioning

confidence: 99%

“…Zirconium and hafnium have a separation factor of 9.2 under these circumstances, and the highest extraction percentage is 96.58 %. Kabangu et al 16) carried out another study on the separation of Zr and Hf by extracting zirconium using 1-octanol. The organic phase is applied to recover zirconium.…”

Section: Introductionmentioning

confidence: 99%

See 4 more Smart Citations

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Rozana,

Dewi,

Poernomo

et al. 2024

Korean. J. Mater. Res.

View full text Add to dashboard Cite

Section: Effect Of Ratio Organic and Aqueous Phase (O/a)mentioning

confidence: 54%

Section: Extraction Of Zr and Hfmentioning

confidence: 99%

Section: Effect Of Ratio Organic and Aqueous Phase (O/a)mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Rozana,

Dewi,

Poernomo

et al. 2024

Korean. J. Mater. Res.

View full text Add to dashboard Cite

Efficient Extraction of [Bmim]BF₄ by Organic-Aqueous System of NaBr-H₂O and CH₂Cl₂

Wu,

Wang,

Zou

et al. 2024

J. Chem. Eng. Data

View full text Add to dashboard Cite

The homogeneous [Bmim]BF 4 -NaBr-H 2 O system will be obtained in the industrial synthesis of [Bmim]BF 4 , and the extraction of [Bmim]BF 4 from such a system remains to be challenging. In this work, dichloromethane (CH 2 Cl 2 ), is used as the organic phase to extract and separate [Bmim]BF 4 (1-butyl-3methylimidazolium tetrafluoroborate) from the reaction solution. Dichloromethane, serving as the extracting agent, effectively facilitates the purification and component separation of the ionic liquid [Bmim]BF 4 postreaction, enhancing the reaction efficiency and product purity. The influence of operating parameters, including initial concentration of the ionic liquid (IL), temperature, O/A ratio (the volume ratio of organic phase to aqueous phase), and initial concentration of NaBr, on IL separation and extraction were investigated. It was found that the recovery ratio of IL and the separation factor could reach 90.3% and 133.19 at optimized extraction conditions. Moreover, this method was appropriate for the extraction of [Bmim]BF 4 at different concentrations. As a result, this work developed an optimized extraction scheme to maximize the yield of [Bmim]BF 4 using an organic and aqueous two-phase system of NaBr-H 2 O and CH 2 Cl 2 , which could provide essential technological parameters for the efficient extraction of [Bmim]BF 4 in the NaBr-H 2 O-CH 2 Cl 2 two-phase system.

show abstract

Solvent extraction of europium(III) from technogenic solutions with the use of surfactants

Dzhevaga

Lobacheva

2020

Fine Chem. Technol.

View full text Add to dashboard Cite

Objectives. The extraction and separation of rare-earth metals is a complicated process that requires a multidisciplinary and detailed investigation. Liquid-liquid extraction with the use of surfactant, along with the thermodynamic analysis of the parameters is considered a promising approach. The extraction and separation of rare-earth metals from low-concentration solutions represents an attractive research opportunity. The extraction of europium(III) from nitric acid solutions in the form of dodecyl sulfates has been experimentally studied. This work focuses on the study of fundamental and alternative sources of rare-earth metals and their extraction and separation.Methods. The extraction was performed on a top drive ES-8300 D equipment for 30 min at about 700 rpm. Infrared spectroscopy (Nicolet 6700 spectrometer) was used to determine the type of salts extracted into the organic phase. Extraction was studied in solutions with single cations and with a combination of the target element and interfering cations. For the latter, the concentrations of extracted elements in the aqueous phase were determined by optical emission spectroscopy with inductively coupled plasma on an ICPE-9000 (Shimadzu) spectrometer. The spectrometer was calibrated using standard samples for ICP CertiPUR (Merck).Results. The dependence of the distribution and separation coefficients of rare-earth metals during extraction on the pH value of the aqueous phase at equilibrium was investigated. Moreover, the form in which the elements are extracted was analyzed based on thermodynamic parameters. The minimum concentration of the target component in the aqueous phase was observed at pH 4.0. In general, the dependence of the distribution coefficient on the pH value of the medium is poorly expressed over the entire range of the pH range of the water phase. Based on the spectra of spent and pure isooctyl alcohol, it was concluded that europium dodecyl sulfates are extracted into the organic phase as Eu(C12H25OSO3) 3 solvates.Conclusions. The extraction of europium(III) from nitric acid solutions in the form of dodecyl sulfates was demonstrated. The advantages of the proposed method are the possibility of selective extraction of the target component from dilute solutions and the use of an easily available surfactant (sodium dodecyl sulfate). The efficiency of extraction of europium dodecyl sulfates was maximal in the pH range from 2.0 to 7.5, which reflects a weak dependence on the acidity of the aqueous phase. In addition, in the highly alkaline pH region, the extraction efficiency is reduced.

show abstract

Extraction and Separation of Zirconium Using 1-Octanol

Cited by 3 publications

References 30 publications

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Efficient Extraction of [Bmim]BF₄ by Organic-Aqueous System of NaBr-H₂O and CH₂Cl₂

Solvent extraction of europium(III) from technogenic solutions with the use of surfactants

Contact Info

Product

Resources

About

Extraction and Separation of Zirconium Using 1-Octanol

Cited by 3 publications

References 30 publications

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

Efficient Extraction of [Bmim]BF4 by Organic-Aqueous System of NaBr-H2O and CH2Cl2

Solvent extraction of europium(III) from technogenic solutions with the use of surfactants

Contact Info

Product

Resources

About

Efficient Extraction of [Bmim]BF₄ by Organic-Aqueous System of NaBr-H₂O and CH₂Cl₂