“…The radiochemical separation procedure of 93 Zr was therefore based on it. But for further purification prior to LSC measurement, a TBP extraction [6] step was chosen between the first and second silica gel adsorption. The procedure adopted was then as follows.…”
Liquid samples of 93 Zr were isolated from high level liquid wastes (HLLW) by means of silica gel adsorption combined with tri-N-butyl-phosphate (TBP) extraction. Thereafter its radioactivity was determined by liquid scintillation counting (LSC) and its mass concentration by multi-collector inductively coupled plasma spectrometry (MC-ICP-MS). So a new value of 93 Zr half-life was found to be (1.13 ± 0.11) × 10 6 a.
“…The radiochemical separation procedure of 93 Zr was therefore based on it. But for further purification prior to LSC measurement, a TBP extraction [6] step was chosen between the first and second silica gel adsorption. The procedure adopted was then as follows.…”
Liquid samples of 93 Zr were isolated from high level liquid wastes (HLLW) by means of silica gel adsorption combined with tri-N-butyl-phosphate (TBP) extraction. Thereafter its radioactivity was determined by liquid scintillation counting (LSC) and its mass concentration by multi-collector inductively coupled plasma spectrometry (MC-ICP-MS). So a new value of 93 Zr half-life was found to be (1.13 ± 0.11) × 10 6 a.
“…The extractability of Zr with dibutyl phosphate increased with increasing U concentrations in HN03 solutions (89). Zirconium may be extracted with dibutyl phosphate in chloroform from fiuoboric-HCl media and be directly determined in the organic phase as the PAN complex (423). Copper, Co, and Ni are extracted into di-2-ethylhexyl phosphate in kerosine as simple complexes; Na is transferred in a micellar complex (288).…”
“…HCl-tributyl phos- (123) phate Tri-.V-octylphos- Extn. with di-n- (165) butyl phosphate employing a combination of microdiffusion with isotope dilution (151).…”
Fobthe past two years, inorganic microchemistry has progressed steadily, but without spectacular innovations. Anyone following the literature closely must be impressed with the growing interest in microchemical and ultramicrochemical methods.
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