Extractive Spectrophotometric Determination of Bismuth(III) in Water Using Some Ion Pairing Reagents

Bashammakh, Abdulaziz S.

doi:10.1155/2011/672076

Cited by 9 publications

(3 citation statements)

References 15 publications

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“…Better sensitivity was observed on the sensor device fabricated with Pt–Ni-12h; i.e., a higher slope of (3.04 ± 0.18) × 10 –5 mA cm –2 ppm –1 was obtained compared to that of (2.57 ± 0.22) × 10 –5 mA cm –2 ppm –1 obtained at the Pt/C-based sensor. The limit of detection (LOD, 3s y/x /b) , of Pt/C and Pt–Ni-12 h based sensors were 218.46 and 131.91 ppm, respectively, as calculated from the calibration curves using the formula s y / x / b (where s y / x is the standard deviation of the y -residual and b is the sensitivity). The Pt–Ni-12h-based sensor device exhibited highly sensing performance which was comparable to that of electrochemical sensors developed by others (Table S2)…”

Section: Resultsmentioning

confidence: 99%

Platinum–Nickel Bimetallic Nanosphere–Ionic Liquid Interface for Electrochemical Oxygen and Hydrogen Sensing

Liu

Chen

et al. 2019

ACS Appl. Nano Mater.

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By exploiting the benefits of bimetallic platinum–nickel (Pt–Ni) alloy nanosphere and an ionic liquid (IL) (i.e., 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (BmpyNTf2), an organic–inorganic hybrid interface of IL/Pt–Ni was designed and characterized for electrochemical sensing of oxygen and hydrogen gases for miniaturized electrochemical gas sensor development. The spherical Pt–Ni alloy nanoparticles (NPs) were synthesized through template-free, one-pot solvothermal method. The morphology, crystal structure, and chemical composition of Pt–Ni alloy NPs were thoroughly characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The obtained Pt–Ni alloy NPs were used to fabricate the planar sensor devices and tested for oxygen and hydrogen sensing. The oxygen-sensing performance of the resulting planar electrochemical sensor was investigated over a low concentration range of 500–5000 ppm of O2 at room temperature by using constant potential amperometry. The planar electrochemical sensor device exhibited a high sensitivity to O2 ((3.04 ± 0.18) × 10–5 mA cm–2 ppm–1) compared to commercial Pt/C-based sensor ((2.57 ± 0.22) × 10–5 mA cm–2 ppm–1). The planar electrochemical sensor device also showed good reproducibility and selectivity for oxygen detection during sensing tests. Moreover, the sensor device based on the obtained Pt–Ni alloy NPs was investigated for hydrogen detection with excellent analytical performance in hydrogen sensing. The outstanding gas sensing properties were attributed to unique interface properties and highly efficient catalytic reaction of gas species of oxygen and hydrogen at the interface of IL/Pt–Ni alloy NPs. This work demonstrated that the integration of Pt–Ni alloy NPs with ILs enabled beneficial electrode interface for O2 and H2 gases sensing with high sensitivity, rapid gas response, and superior reproducibility based on a novel planar electrochemical sensor platform.

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Section: Resultsmentioning

confidence: 99%

Platinum–Nickel Bimetallic Nanosphere–Ionic Liquid Interface for Electrochemical Oxygen and Hydrogen Sensing

Liu

Chen

et al. 2019

ACS Appl. Nano Mater.

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“…Bismuth presents in two oxidation state three and five, its compounds are not exist in solution and are very important in view of analytical chemistry [1].Although bismuth was not known as a metal, it was used as a beauty treatment during [2]. Bismuth and its compound are also used in semiconductors cosmetic preparations, alloys and metallurgical additives and in the preparation and recycling of uranium nuclear fuels [3].…”

Section: Introductionmentioning

confidence: 99%

“…Bismuth and its compound are also used in semiconductors cosmetic preparations, alloys and metallurgical additives and in the preparation and recycling of uranium nuclear fuels [3]. The development of analytical techniques for the determination of bismuth at low levels by analytical techniques such as spectrophotometry [4][5][6][7], graphite furnace atomic absorption spectrometry [8,9], voltammetry [10,11] and inductively coupled plasma mass spectrometry [12] have been used for its measurement. Several procedure have been developed for the separation and preconcentration of contaminants from environmental matrices such as liquid -liquid extraction [13], coprecipitation [14], solid phase extraction [ 15].…”

Section: Introductionmentioning

confidence: 99%

Quantitative Analysis of Bismuth (III) Ion by Coupling Turbidy Method with Cloud Point Extraction Mode

2016

IJSR

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Abstract:A new turbidimetric method is described for the determination of bismuth(III) ion .This method is based reaction between Bi(III) ion with fuchsine reagent and Sodium dodecyl sulfate (SDS) as a surfactant compound in aqueous medium to form red ion-pair complex as turbid phase .The product was determined by using batch turbidimatric method.. All optimization parameters were studied. The calibration graph was linear in the range of (0.05 -25)µg.mL -1 , with correlation coefficient r =0.9973 and limit of detection (0.047 µg.mL -1 ).A comparison was made between the newly developed method analysis with classical method using standards addition method via the use of t-test it was noticed that there was no significant difference between two methods at %95 confidence level.

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Statistically designed extractive spectrophotometric determination scheme for bismuth(III) with 2-chlorobenzaldehyde thiocarbohydrazone: Analysis of environmental and real resources

Sadlapurkar¹,

Barache²,

Shaikh³

et al. 2022

Chemical Data Collections

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Extractive Spectrophotometric Determination of Bismuth(III) in Water Using Some Ion Pairing Reagents

Cited by 9 publications

References 15 publications

Platinum–Nickel Bimetallic Nanosphere–Ionic Liquid Interface for Electrochemical Oxygen and Hydrogen Sensing

Platinum–Nickel Bimetallic Nanosphere–Ionic Liquid Interface for Electrochemical Oxygen and Hydrogen Sensing

Quantitative Analysis of Bismuth (III) Ion by Coupling Turbidy Method with Cloud Point Extraction Mode

Statistically designed extractive spectrophotometric determination scheme for bismuth(III) with 2-chlorobenzaldehyde thiocarbohydrazone: Analysis of environmental and real resources

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