In the past years, the interest in the laser-driven acceleration of heavy ions in the mass range of A ≈ 200 has been increasing due to promising application ideas like the fission-fusion nuclear reaction mechanism, aiming at the production of neutron-rich isotopes relevant for the astrophysical r -process nucleosynthesis. In this paper, we report on the laser acceleration of gold ions to beyond 7 MeV/u, exceeding for the first time an important prerequisite for this nuclear reaction scheme. Moreover, the gold ion charge states have been detected with an unprecedented resolution, which enables the separation of individual charge states up to 4 MeV/u. The recorded charge-state distributions show a remarkable dependency on the target foil thickness and differ from simulations, lacking a straight-forward explanation by the established ionization models.Promising application perspectives for laser-accelerated heavy ions in the mass range of A ≈ 200 led to an awakening interest in laser-based heavy ion acceleration. Since 2015, multiple experimental papers reported on progress in laser-driven acceleration of gold ions, pushing the achieved kinetic energies from 1 MeV/u [1] to 5 MeV/u [2] to finally 6.1 MeV/u [3]. This evolution has been accompanied by several simulations [4-6], which especially studied the expected gold ion charge-state distributions based on the established models of tunnel and electron impact ionization.With this paper, we pursue the long-term goal of realizing the fission-fusion reaction mechanism proposed already a decade ago [7]. This aims at the production of extremely neutron-rich isotopes close to the waiting point of the rapid neutron capture (r -)process at the magic neutron number N = 126 [8], which is a decisive region for the astrophysical nucleosynthesis of the heaviest elements in the Universe. The fission-fusion reaction mechanism is a two-step process, which is expected to be enabled to occur when ultra-dense bunches of laser-accelerated heavy, fissile ions (like 232 Th) with kinetic energies above the fission barrier impinge on a target consisting of the same material. In a first step, both projectile and target ions undergo fission. Afterwards, fusion of fission fragments may happen, in case of fusion between two light fission fragments the desired neutron-rich r -process isotopes are formed. This reaction scheme requires the application of laser-accelerated heavy ion bunches owing to their ultra-high, almost solid-state-like density which is expected when accelerating in the regime of radiation pressure acceleration (RPA) [9][10][11][12]. The densities of ion bunches delivered by conventional accelerators are orders of magnitude lower and thus insufficient to