We present measurements of the rest-frame UV spectral slope, β, for a sample of 36 faint star-forming galaxies at z ∼ 9–16 discovered in one of the deepest JWST NIRCam surveys to date, the Next Generation Deep Extragalactic Exploratory Public Survey. We use robust photometric measurements for UV-faint galaxies (down to M
UV ∼ −16), originally published in Leung et al., and measure values of the UV spectral slope via photometric power-law fitting to both the observed photometry and stellar population models obtained through spectral energy distribution (SED) fitting with Bagpipes. We obtain a median and 68% confidence interval for β from photometric power-law fitting of
β
PL
=
−
2.7
−
0.5
+
0.5
and from SED fitting,
β
SED
=
−
2.3
−
0.1
+
0.2
for the full sample. We show that when only two to three photometric detections are available, SED fitting has a lower scatter and reduced biases than photometric power-law fitting. We quantify this bias and find that after correction the median
β
SED
,
corr
=
−
2.5
−
0.2
+
0.2
. We measure physical properties for our galaxies with Bagpipes and find that our faint (
M
UV
=
−
18.1
−
0.9
+
0.7
) sample is low in mass (
log
[
M
*
/
M
⊙
]
=
7.7
−
0.5
+
0.5
), fairly dust-poor (
A
v
=
0.1
−
0.1
+
0.2
mag), and modestly young (
log
[
age
]
=
7.8
−
0.8
+
0.2
yr) with a median star formation rate of
log
(
SFR
)
=
−
0.3
−
0.4
+
0.4
M
⊙
yr
−
1
. We find no strong evidence for ultrablue UV spectral slopes (β ∼ −3) within our sample, as would be expected for exotically metal-poor (Z/Z
⊙ < 10−3) stellar populations with very high Lyman continuum escape fractions. Our observations are consistent with model predictions that galaxies of these stellar masses at z ∼ 9–16 should have only modestly low metallicities (Z/Z
⊙ ∼ 0.1–0.2).