The fusion of monopulse laser rangefinder and optical camera information requires the acquisition of their relative pose and attitude parameters. This paper focuses on the relative pose calibration of monopulse laser rangefinder (MLRF) and visible light array camera. Two calibration methods are proposed. The image plane of the infrared camera and the physical plane whose pose of the visible array camera is known are locally registered to solve the difficulty of the calibration of the laser spot relative to the invisible of the visible array camera. Then evaluate the stability of the pose solution of exceed the calibration distance. The experimental results show that the reprojection error of the relative pose solution obtained by finite number of measurements is less than 1 pixel. The position error within the calibration distance is less than 4 mm; Beyond the calibration distance, the position error increases by less than 3 mm for per 10 m.