personal protective equipment (PPE) is of vital importance to radiation protection safety of nuclear personnel involved. [4][5][6] Currently, the PPE is fabricated with rubber-based composites containing high atomic number (high Z) fillers such as lead (Pb), tungsten (W), and bismuth (Bi). [7][8][9][10][11] Although it has various merits such as flexibility for wearability, its poor permeability for air and water vapor is negative to channel sweat away during work, which causes reduced wear comfort and then affects working efficiency. [12,13] Therefore, it is urgent to develop flexible materials with permeability for enhanced wear comfort and radiation protection safety of PPE.Many studies have attached importance to fabrics bearing heavy metals to meet the requirements. This is due to the fact that overlapped fabrics shield high-energy photons meanwhile offer curving passages for permeability. Coating high-Z fillers on textiles has the ability to shield highenergy photons while it tends to be peeled off and reduce permeability. [14][15][16][17][18][19] Alternatively, polymer fibers containing high-Z fillers for fabrics seems to address wear comfort meanwhile radiation shielding safety. Some high-Z fillers, such as Bi 2 O 3 , WO 3 , Bi 2 WO 6 , and BaSO 4 , have been intensely applied to fabricated various polymer fibers for shielding X-rays. [20][21][22][23][24][25] Note that current polymer fibers are generally filled with no more than 40 wt% fillers. This is due