Fabrication and Characterization of Aluminum Nitride/Boron Nitride Nanocomposites by Carbothermal Reduction and Nitridation of Aluminum Borate Powders

Abstract

In order to fabricate aluminum nitride/boron nitride (AIN/BN) nanocomposites by pressureless sintering, the present study investigated the synthesis of AIN-BN nanocomposite powders by carbothermal reduction and nitridation of aluminum borate powders. Homogeneous mixtures of alumina (Al2O3), boric acid (H3BO3), and carbon powder were used to synthesize AIN/BN nanocomposite powders containing 10 and 20 vol% BN. Aluminum borate was produced by reacting Al2O3 and B2O3 above 800 degrees C, and AIN and turbostratic BN (t-BN) were produced by reacting aluminum borate with carbon powder and nitrogen gas at 1500 degrees C. Carbothermal reduction followed by nitridation yielded an AIN/BN nanocomposite powder composed of nanosized AIN and t-BN. By pressureless sintering nanocomposite AIN/BN powders containing 5 wt% Y22O3, AIN/BN nanocomposites were obtained without compromising the high thermal conductivity and high hardness.

Synthesis of β-SiAlON/h-BN nanocomposite by a precursor infiltration and pyrolysis (PIP) route

“…2(c) shows that the powders crushed from pyrolyzed S3 are surrounded with a low contrast phase. The low contrast phase would be turbostratic BN (t-BN) which is the pyrolysing product of precursors [6,18,19]. From Fig.…”