H + -containing lanthanide-doped perovskites A (Ba, Sr etc.)B(Zr, Ce, Ti etc.)O 3 are potential ceramic membranes for fuel cell and medium temperature water electrolysis (300-800°C). The comparison studies of the hydrated and non-hydrated Yb-doped BaZrO 3 and SrZrO 3 were performed by thermal expansion, medium-high temperature neutron and room-temperature high-pressure Raman scattering. Neutron diffraction and elastic/quasielastic studies carried out for BaZrO 3 ceramic show the presence of the protons, their successive diffusion above ∼600°C, and then their departure above 750°C (under vacuum). Phase transitions and their modification by proton insertion are discussed. A high-pressure Raman study of SrZrO 3 performed at room temperature in the diamond anvil cell reveals the presence of two pressure-induced phase transitions at about 5 and 22 GPa and confirms that proton insertion modifies the phase transition sequences.