Crystal-oriented (Bi 0.5 , Na 0.5 ) 1¹x Ba x TiO 3 (BNBT), (x = 0.10.25) ceramics with a perovskite crystal structure were prepared by colloidal processing in a strong rotating magnetic field with the aim of improving their piezoelectric properties. The advantages of increasing the amount of Ba in these ceramics are twofold; specifically, this will lead to anisotropic crystal lattices and it will also increases the tetragonality. The crystaloriented BNBT (x = 0.10.25) ceramics were prepared by using a rotating magnetic field to orient the a-and caxes of the crystal in the powder compact. The degree of orientation also increased with the tetragonality. The phase transformation that occurred above Curie temperature during sintering redistributed the c-axis-oriented structure along both the a-and c-axes. Again, the c-axis orientation was enhanced by electrical field polarization. The piezoelectric d 33 constant, which depended on the Ba content, achieved a maximum value of 122 pC N ¹1 at a Ba content of 15 mol %.