In this study, we
investigated the room-temperature wafer bonding
of indium phosphide (InP) and its atomic-scale bond interface formation.
The direct bonding of InP/InP wafers via surface-activated bonding
(SAB) and room-temperature bonding involving an activated Si atomic
layer was compared. Particularly, the bond strength, surface morphology,
and atomic structure in the bond interface were investigated. In contrast
to SAB, the bonding involving the activated Si atomic layer afforded
more than 2-fold increase in bond strength. This is because, unlike
that in SAB, the InP surface was not directly irradiated by an Ar
fast atomic beam; instead, a layer of activated Si atoms was deposited.
Consequently, the surface roughness of the wafers was lower than that
obtained using SAB. The atomic structure of the wafer surface was
maintained after activation, and atomic contact between the wafers
was achieved. The diffusion of In and P into the Si atomic layers
affected the bond strength, indicating that the InP–InP bonding
in the wafers through an activated Si atomic layer was different from
the simple bonding of two Si bulks. Notably, the state of the bond
interface obtained via SAB was different from that obtained via SAB
of other semiconductor materials. The room-temperature bonding method
will be significantly useful in the development of fabrication techniques
for the heterogeneous integration of InP-based electronics and photonics.