Ethylene
scavengers exhibit considerably high potential for their
application in prolonging the shelf-life of fruits, but their application
has been hindered owing to food safety and environmental issues. Thus,
in this study, we fabricated a bio-based nanofiber film composed of
zein, Artemisia sphaerocephala Krasch. gum (ASKG),
and chitosan (CS) via electrospinning. The addition of ASKG and CS
increased the viscosity and surface tension of zein precursor solutions
and consequently enhanced their spinnability. Electrostatic co-assembly
between the protein and polysaccharides led to the formation core–shell
nanofibers (Z@A-CS nanofibers), which effectively enhanced their ethylene
removal efficiency, mechanical properties, and hydrophobicity. Furthermore,
bananas incubated with the Z@A-CS nanofiber films for 10 days exhibited
a lower browning rate, higher hardness, and prolonged shelf-life compared
to those incubated without a film. Based on these results, we deduce
that the strong interactions between the numerous active functional
groups of zein and ethylene and the large specific surface area of
the nanofibers led to the development of highly efficient, environmentally
friendly, and economical ethylene scavenger films, which exhibit a
high potential in fruit preservation.