Spontaneously
scrolling hydrosilicate nanotubes raise additional
attention due to their sorption, catalytic, and other functional properties.
Layered hydrosilicates like chrysotile and pecoraite form primarily
multiwalled nanotubes and nanoscrolls with relatively wide diameter
and length distributions. To understand the reasons behind these issues
we propose here an energy model of multiwalled nanoscroll formation
and growth that accounts for strain, surface, and adhesion energy
changes. Objects of comparison are chrysotile and pecoraite nanoscrolls,
obtained by hydrothermal synthesis and characterized by X-ray diffraction
and microscopic techniques. Energy modeling reveals a preferable nanoscroll
cross-section consisting of 12 to 13 chrysotile layers or 25 to 26
pecoraite layers. The energy effect of scrolling is relatively low
(3–5 kJ/mol), and the energy minimum becomes broader during
growth.