Fabrication of hybrid proton‐exchange membranes using a brandnew high temperature ionic liquid as charge transporting and clay modifier

Abstract

The search for more compatibility between ionic liquids (ILs) and polymer matrices in proton-exchange membrane fuel cells (PEMFCs) is one of the ways in which IL leaking from proton-exchange membranes could be minimized. In this work, it is presented the synthesis of an aromatic high temperature ionic liquid (HTIL), which, incorporated into an aromatic matrix such as sulfonated polyether ether ketone (sPEEK), is expected to diminish the IL leaking that normally affects PEMFC. Phenylethylammonium trifluoromethane sulfonate (PhetaTfO) was successfully synthesized and characterized. Its melting point of 88 C makes it to classify as a HTIL and it was employed as modifier of natural Montmorillonite, forming the phenylethylammonium intercalated montmorillonite (MmtPheta) and thus, ternary membranes containing PhetaTfO, MmtPheta, and sPEEK were prepared and characterized. Immersion tests demonstrated a higher compatibility of PhetaTfO with matrix when compared to the reference DemaTfO, which was reflected in up to 30% lower IL loss by the synthesized IL than the DemaTfO; X-rays diffraction (XRD) patterns demonstrated that the modified clay was properly dispersed inside the membranes, while dynamic mechanical analyses (DMA) results indicated a strong plasticizer effect along the increase of PhetaTfO content inside the membrane, while at the same time, the conductivity increased in an exponential manner, which permitted to identify an empiric exponential equation to evaluate the effect of concentration on ionic conductivity. The maximum conductivity obtained at IL concentrations of around 38 wt% was 0.2 mS/cm. It could expect high ionic conductivities of 10 mS/cm when the concentration of this IL is 60%; nevertheless, in order to achieve that, crosslinking treatments should be done to give the membranes enough mechanical resistance.

Sulfonated Poly Ether Ether Ketone Membranes Reinforced by Metal–Organic Frameworks/Ionic Liquids

“…Among them, Co-MOF-74, as a ternary membrane proton conduction material, has significant application value in mass transfer under high-temperature conditions. 18 No change in peak position was observed within 20−60 °C, and the diffraction patterns were basically consistent with the previously reported literature data. 19 The slight changes in the intensity of the first diffraction peak that occurred near 6.7°can be attributed to the occupancy of water in the pores.…”

“…The XRD spectra of the prepared MOF-74 material, SPEEK membrane, and ternary composite membrane are shown in Figure a,b. Among them, Co-MOF-74, as a ternary membrane proton conduction material, has significant application value in mass transfer under high-temperature conditions . No change in peak position was observed within 20–60 °C, and the diffraction patterns were basically consistent with the previously reported literature data .…”