Negative permittivity is one of the key characteristics of the unique metamaterials, a novel class of artificial materials with special structures that simultaneously exhibit negative permittivity and permeability. In metamaterials, adherence to the right-hand rule, which is obligatory for all other materials working in an electromagnetic field (electric field E, magnetic field H), does not apply. The wave vector k in metamaterials is consistent with a left-handed rule, and, hence, this special class of materials is also called left-handed materials (LHM), first theoretically proposed by Veselago in 1960s.[1] The negative permittivity and negative permeability endow LHM with several special properties, such as negative refractive index, reversed Doppler Effect, and reversed Cherenkov radiation, [2] none of which exist in natural materials. Metamaterials can be applied in sub-wavelength imaging, cloaking, wave filter, super lens, and band-gap design. [3][4][5] Since 2000, when investigations of metamaterials were experimentally performed by double-slit-ring resonator and linear vibrator, [6] research on the construction and application of metamaterials in optical and microwave frequencies range have attracted great interest, and much theoretical work has been published; however, the realization of their promise still requires great effort.It is well recognized that the unusual properties of metamaterials are determined by their specially designed structures, rather than their compositions. In other words, the permittivity and/or permeability are not, or are just weakly, dependent on chemical structures and constituent compositions, or interactions among different components in the materials. Various structures have been designed by physicists and electrical engineers to obtain negative permittivity and negative permeability, including double-split-ring resonators, [3] S-shaped resonators, [7] multilevel dendritic structures, [2] nano/small apertures, [8,9] metallic nanoclusters, [5] among others. In all of these, resonance was considered to be the main mechanism of the realization of both negative permittivity and negative permeability, while the phase changes close to the resonant frequency.[10] In contrast, the exploration of metamaterials from the point of view of materials (chemistry and properties) has not attracted substantive attention from material researchers. Among the very limited work reported, almost all research in this field focused on metals and ceramics, which contain metallic elements and can consequentially realize negative permittivity and/or permeability under certain conditions. In particular, ferromagnetic materials were the subject of considerable interests in realization of metamaterials, owing to the resultant negative permittivity of metallic materials below plasma frequency as well as negative permeability of some ferromagnetic metals and metallic alloys in the vicinity of the ferromagnetic resonance frequency. [11][12][13] However, to the best of our knowledge, research has been rarely...