“…9–12 However, current fiber spinning methods lack the ability to precisely control both the macro- and microstructures of fibrous aerogels simultaneously. Post shaping of these fibrous aerogels would result in fluctuations in interlayer spaces or thicknesses, 13,14 consequently impeding the overall performance of the material. Hence, further optimization of the spinning process to control the architecture and microstructure of 3D fibrous aerogels is crucial for enhancing their application potential.…”