Highly porous Germanium surfaces with uniformly distributed columnar nanovoid structures are fabricated over a large area (wafer scale) by large fluence Sn+ irradiation through a thin silicon nitride layer. The latter represents a one-step highly reproducible approach with no material loss to strongly increase photon harvesting into a semiconductor active layer by exploiting the moth-eye anti-reflection effect. The ion implantation through the nitride cap layer allows fabricating porous nanostructures with a high aspect ratio, which can be tailored by varying ion fluence. By comparing the reflectivity of nanoporous Ge films with a flat reference we demonstrate a strong and omnidirectional reduction in the optical reflectivity by a factor 96% in selected spectral regions around 960nm and by a factor 67.1% averaged over the broad spectral range from 350nm to 1800 nm. Such highly anti-reflective nanostructured Ge films prepared over large areas with a self-organized maskless approach have the potential to impact real-world applications aiming at energy harvesting.