Fabrication of NiCo₂O₄@polyaniline heterostructure as positive electrode for asymmetrical supercapacitor

Abstract

NiCo2O4, as a low‐cost and high‐performance binary transition metal oxide material, has been widely used in the fabrication of supercapacitor electrodes. However, the low energy density of binary metal oxides limits their large‐scale practical applications in supercapacitors, so it is highly desirable to design the structure of the NiCo2O4‐based supercapacitor. Therefore, in this paper, NiCo2O4 is compounded with polyaniline (PANI) to improve its electrochemical performance by exploiting the synergistic effect. The NiCo2O4@PANI composite electrode exhibits a specific capacitance of 561.2 F/g at 10 mV/s. In this study, asymmetric supercapacitors are assembled with NiCo2O4@PANI as the positive electrode and MXene as the negative electrode. The NiCo2O4@PANI‐CC//MXene‐CC supercapacitor has a specific capacitance of 31.95 F/g at a scan rate of 10 mV/s and a good cycle retention capacity of 86.2% after 3000 cycles. The excellent electrochemical performances are attributed to the dynamic equilibrium and fast redox kinetics of the two electrodes.

Polypyrrole and activated carbon enriched MnCo2O4 ternary composite as efficient electrode material for hybrid supercapacitors

“…The addition of PPY enhances the redox behavior of the pristine MnCo 2 O 4 , as supported by the literature. 67–70 The MAP-20 exhibited the highest diffusive character among all the samples. Furthermore, the Trasatti method is used to identify the contribution of inner and outer surfaces to the total capacitance.…”

“…Table S3 in ESI† provides the supercapacitive performance of some recently reported PPY-based composites of BTMOs and their comparison with present work. 39,41,68,78–89 The comparison shows that the synthesized composited exhibited remarkable electrochemical performance making it a promising electrode material for energy storage applications.…”