Fabrication of Strontium Bismuth Oxides as Novel Battery-Type Electrode Materials for High-Performance Supercapacitors

Abstract

A simple and efficient process method for the preparation of strontium bismuth oxides (SBOs) via an impregnation-calcination method is presented. The synthesized active materials are characterized using X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. The electrochemical performance of the as-synthesized SBO samples is observed to decrease gradually as the strontium content is increased from 25% to 50%. The SBO sample with a Sr/Bi ratio of 1 : 3 shows the highest specific capacitance of 1228.7 F g−1 (specific capacity of 204.8 mAh g−1) at a current density of 1 A g−1 and a good cycling stability (75.1%) over 3000 charge-discharge cycles. The improved performance of the supercapacitors can be attributed to the unique structural features resulting from the addition of appropriate portions of Sr, which supports high electron conductivity and rapid ion/electron transport within the electrode and at the electrode/electrolyte interface. All the results show that the SBOs have considerable potential for use as high-performance battery-type electrodes in supercapacitors.

Mesoporous Nickel-Based Zeolite Capsule Complex with Fe3O4 as Electrode for Advanced Supercapacitor

“…To further identify the crystal structure and phase composition of all the samples, X-ray diffraction (XRD) analyses were carried out. As shown in Figure 5, those are the X-ray diffraction patterns of the pure Fe 3 The morphological specific surface area and crystal structure were detected by SEM, HRTEM, N 2 adsorption analyses, and XRD, respectively. It can be well prepared for further analysis of the energy storage mechanism of the sample.…”

“…where C high and C low are the values of specific capacitance at −0.1 V and 0.3 V calculated by (3). β is the capacitance retention.…”

“…Therefore, developing energy storage technology is an important guarantee for the popularization and application of new energy and renewable energy. As a power storage technology, supercapacitors have attracted much attention in terms of its high power density, fast charge and discharge rate, and long cycle life [1][2][3][4][5]. According to different energy storage mechanisms, the supercapacitors can be divided into double-layer capacitors (EDLCs) and pseudocapacitors [6,7].…”