Capacitors based on ionic liquid gel polymer electrolytes (GPEs) have received wide attention as an environmentally friendly energy source due to their good speci c capacitance, good cycling capacity, and stability. Herein, exible gel polymer electrolyte (GPE) lms were prepared and applied using three butyl imidazole ionic liquids containing different anions as additives based on polyvinylidene uoride hexa uoropropylene (PVDF-HFP). The structural and mechanical properties of GPE lms have been characterized by SEM, XRD, FTIR, TGA, stress-strain, and DFT calculations, and their ionic conductivity has been tested by stainless steel methods. The assembled symmetric supercapacitor underwent testing via cyclic voltammetry, electrochemical impedance, and constant current charge-discharge methods. The objective was to assess the impact of various gel electrolytes utilized in the experiment. This work is useful to further verify the in uence of the anionic component of ionic liquids on the physical and chemical properties of gel electrolytes and to prepare more excellent solid electrolytes for supercapacitors.