Ce: YIG thin-film is an ideal candidate for magneto-optical devices with giant Faraday effect in the near-infrared range, but is hindered by a limited Ce3+ / Ce4+ ratio and a high saturation driving field. To address this issue, Eu doping increased the Faraday rotation angle by ~ 40% to 1.315×104 deg/cm and decreased the saturation driving field by ~ 38% to 1.17 kOe in Eu0.75Ce1Y1.25Fe5O12relative to Ce1Y2Fe5O12 pristine. The mechanism is attributed to the conversion of Ce4+ to Ce3+ and the weakening of ferrimagnetism by Eu doping. This work not only provides strategies for improving Ce3+/Ce4+ ratio in Ce: YIG, but also develops (Eu, Ce): YIG with promising Faraday rotation angle for magneto-optical devices.