Faceting and structural anisotropy of nanopatterned CdO(110) layers

Abstract

CdO͑110͒ layers with a self-organized surface structure have been grown on ͑1010͒ sapphire ͑m plane͒ substrates by metal-organic vapor phase epitaxy. The epitaxial relationships between layer and substrate have been determined and a crystallographic model that accounts for the CdO in-plane orientation, which results in a reduced lattice mismatch when the CdO͓001͔ direction is perpendicular to the sapphire c axis, has been proposed. Although the measured lattice parameters indicate that the layers are almost fully relaxed, an anisotropic mosaicity is detected with symmetrical rocking curves attaining minimum values when measured along the CdO͓110͔ direction. The layer morphology consists of a regular ridge-and-valley structure which defines, again, a preferential in-plane direction. The grooves run parallel to the CdO͓001͔ axis and exhibit lateral surfaces sloped at 28°with respect to the ͑110͒ surface. The influence of growth temperature and VI/II molar ratio on the anisotropic mosaicity and morphology has been analyzed.