Facial fabrication of few-layer functionalized graphene with sole functional group through Diels–Alder reaction by ball milling

Yu, Wenguang; Gao, Xuefeng; Yuan, Zhicheng; Liu, Haihui; Wang, Xuechen; Zhang, Xingxiang

doi:10.1039/d2ra01668k

Cited by 1 publication

(1 citation statement)

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“…Ball milling is a simple and environmentally friendly strategy to exfoliate graphite, synthesize graphene and graphene-based materials, and pre-pare graphene oxides. Few-layer functionalized graphene with a sole functional group [124] and edge-carboxylate graphene (ECG) [125] were obtained by means of dry ball milling graphite powders with milling balls. Chandran et al [126] found that D-sorbitol could assist in the ball milling of graphite to graphene, and the polyhydric nature of D-sorbitol was able to insert and interact with layers via non-conventional OH-π and CH-π H-bonding.…”

Section: Ball-milled Graphene-based Materialsmentioning

confidence: 99%

Recent Advances in Ball-Milled Materials and Their Applications for Adsorptive Removal of Aqueous Pollutants

Gao,

Fan,

Sun

et al. 2024

Water

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Ball milling, as a cost-effective and eco-friendly approach, has been popular in materials synthesis to solve problems involving toxic reagents, high temperatures, or high pressure, which has the potential for large-scale production. However, there are few reviews specifically concentrating on the latest progress in materials characteristics before and after ball milling as well as the adsorptive application for aqueous pollutants. Hence, this paper summarized the principle and classification of ball milling and reviewed the advances of mechanochemical materials in categories as well as their adsorption performance of organic and inorganic pollutants. Ball milling has the capacity to change materials’ crystal structure, specific surface areas, pore volumes, and particle sizes and even promote grafting reactions to obtain functional groups to surfaces. This improved the adsorption amount, changed the equilibrium time, and strengthened the adsorption force for contaminants. Most studies showed that the Langmuir model and pseudo-second-order model fitted experimental data well. The regeneration methods include ball milling and thermal and solvent methods. The potential future developments in this field were also proposed. This work tries to review the latest advances in ball-milled materials and their application for pollutant adsorption and provides a comprehensive understanding of the physicochemical properties of materials before and after ball milling, as well as their effects on pollutants’ adsorption behavior. This is conducive to laying a foundation for further research on water decontamination by ball-milled materials.

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Section: Ball-milled Graphene-based Materialsmentioning

confidence: 99%

Recent Advances in Ball-Milled Materials and Their Applications for Adsorptive Removal of Aqueous Pollutants

Gao,

Fan,

Sun

et al. 2024

Water

View full text Add to dashboard Cite

show abstract

Facial fabrication of few-layer functionalized graphene with sole functional group through Diels–Alder reaction by ball milling

Abstract: The widespread use of graphene as a next-generation material in various applications requires developing an environmentally friendly and efficient method for fabricating functionalized graphene.

Cited by 1 publication

References 50 publications

Recent Advances in Ball-Milled Materials and Their Applications for Adsorptive Removal of Aqueous Pollutants

Recent Advances in Ball-Milled Materials and Their Applications for Adsorptive Removal of Aqueous Pollutants

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