2023
DOI: 10.1002/cssc.202300225
|View full text |Cite
|
Sign up to set email alerts
|

Facile Access to CO2‐Sourced Polythiocarbonate Dynamic Networks And Their Potential As Solid‐State Electrolytes For Lithium Metal Batteries

Abstract: Poly(monothiocarbonate)s are an interesting class of sulfurcontaining materials whose application as solid polymer electrolytes was barely studied, certainly due to the elusive production of diversified polymer architectures. Herein, a new liquid CO 2 -sourced bis(α-alkylidene cyclic carbonate) monomer was designed at high yield to allow its one-step and solventfree copolymerization with thiols to produce linear and crosslinked polymers in mild conditions. The influence of the monomer structure on the thermal … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
7
0

Year Published

2023
2023
2025
2025

Publication Types

Select...
5

Relationship

2
3

Authors

Journals

citations
Cited by 5 publications
(7 citation statements)
references
References 48 publications
0
7
0
Order By: Relevance
“…with amines, 50,51 with alcohols 52 and thiols. 53 The scope of the obtained polymers was further expanded by different groups to bring more diversification, tunability, functionality, and emerging applications 54–58 without omitting recyclability. 42,59,60…”
Section: Introductionmentioning
confidence: 99%
“…with amines, 50,51 with alcohols 52 and thiols. 53 The scope of the obtained polymers was further expanded by different groups to bring more diversification, tunability, functionality, and emerging applications 54–58 without omitting recyclability. 42,59,60…”
Section: Introductionmentioning
confidence: 99%
“…The dehydrated polymer P4 displayed a single mass loss at a T deg10% of 342 °C (Figure c) and two glass transition temperatures at T g,1 = 18 °C and T g,2 = 100 °C (Figures d and S37). The presence of the two T g s was an uncommon feature already observed for other oxazolidone-containing polymers. , They are assumed to originate from two amorphous glassy phases with the hydroxyoxazolidone linkages that are responsible for the high- T g due to increased backbone rigidity and hydrogen bonding.…”
mentioning
confidence: 95%
“…The presence of the two T g s was an uncommon feature already observed for other oxazolidone-containing polymers. 19,44 They are assumed to originate from two amorphous glassy phases with the hydroxyoxazolidone linkages that are responsible for the high-T g due to increased backbone rigidity and hydrogen bonding.…”
mentioning
confidence: 99%
See 2 more Smart Citations