2017
DOI: 10.1016/j.apcatb.2016.06.071
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Facile assembly of Bi2O3/Bi2S3/MoS2 n-p heterojunction with layered n-Bi2O3 and p-MoS2 for enhanced photocatalytic water oxidation and pollutant degradation

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Cited by 335 publications
(105 citation statements)
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“…Theoretically, adequate amounts of p-n heterojunctions between (001) facets of BiOCl and (002) facets of g-C 3 N 4 are formed during the synthetic process, which facilitates electrons from the n-type C 3 N 4 in the heterostructure interfaces transferring to the p-type BiOCl. Actually, the holes are inclined to stay at lower energy states, leading to the fact that the status of positively charged holes in the p-type BiOCl and extra negatively charged electrons in the n-type C 3 N 4 will be achieved [59]. Consequently, an internal electric field is simultaneously formed with a positively charged portion at the interface of p-type BiOCl nanoplates and a negatively charged portion at the interface of n-type g-C 3 N 4 nanosheets, and the direction of the internal electric field is from n-type g-C 3 N 4 to p-type BiOCl.…”
Section: Catalyst Photostability and Photocatalytic Mechanismmentioning
confidence: 99%
“…Theoretically, adequate amounts of p-n heterojunctions between (001) facets of BiOCl and (002) facets of g-C 3 N 4 are formed during the synthetic process, which facilitates electrons from the n-type C 3 N 4 in the heterostructure interfaces transferring to the p-type BiOCl. Actually, the holes are inclined to stay at lower energy states, leading to the fact that the status of positively charged holes in the p-type BiOCl and extra negatively charged electrons in the n-type C 3 N 4 will be achieved [59]. Consequently, an internal electric field is simultaneously formed with a positively charged portion at the interface of p-type BiOCl nanoplates and a negatively charged portion at the interface of n-type g-C 3 N 4 nanosheets, and the direction of the internal electric field is from n-type g-C 3 N 4 to p-type BiOCl.…”
Section: Catalyst Photostability and Photocatalytic Mechanismmentioning
confidence: 99%
“…Meanwhile, the peaks were not very sharp, which pointed at low crystallinity of the sample [16]. This phenomenon might result from the addition of WO3 to CeO2 as reported in literature, which was regarded to be an indication of strong interactions between the metal oxides [22]. For Fe0.5-W-Ce catalyst, no new peaks appear, but the CeO2 and WO3 peaks became less intense and broader.…”
Section: Bet and Xrdmentioning
confidence: 84%
“…For Fe0.5-W-Ce catalyst, no new peaks appear, but the CeO 2 and WO 3 peaks became less intense and broader. This was reflected by the small crystallite size of the sample, which was usually associated with a high catalytic performance [22]. In addition, two possible explanations were given for the absence of new peaks from Fe compounds in Fe0.5-W-Ce.…”
Section: Bet and Xrdmentioning
confidence: 99%
“…In Figure 4, it is observed that the obvious peaks at 143, 397, and 515 cm −1 are attributed to the characteristic Eg(1), B1g(1), and A1g + B1g(2) vibration of anatase TiO2, respectively [26]. In the case of MoS2, the peaks at 375 and 405 cm −1 are ascribed to the typical E 1 2g and A1g vibration modes, respectively [31]. It is well-known that the E 1 2g vibration mode associates with in-layer displacements of Mo and S atoms while A1g is related to out of layer symmetric displacements of S atoms along c axis.…”
Section: Synthesis and Characterizations Of Mos 2 /Tio 2 Nbs Heterojumentioning
confidence: 95%
“…73-1508), whereas the crystallinity of MoS 2 nanotubes is relatively low, resulting in broadened diffraction peaks due to lack of high temperature annealing. As shown in Figure 1, three obvious peaks at 16.4 • , 32.7 • , and 56.9 • are ascribed to the characteristic (002), (100), and (110) facets, respectively [30,31]. After in situ growth of MoS 2 by means of adding TiO 2 as a precursor, the characteristic diffraction peaks of MoS 2 and TiO 2 can be observed in the XRD pattern of the as-obtained composite in Figure 1, which indicates that MoS 2 and TiO 2 exist together in the composite.…”
Section: Synthesis and Characterizations Of Mos 2 /Tio 2 Nbs Heterojumentioning
confidence: 99%